研究论文

  • 陈静生,张国梁,穆岚,霍文毅,杨本津.土壤对六价铬的还原容量初步研究[J].环境科学学报,1997,17(3):334-339

  • 土壤对六价铬的还原容量初步研究
  • REDUCTION CAPACITIES OF SOIL FOR Cr(VI)
  • 基金项目:国家自然科学基金, 国家“八五”科技攻关项目
  • 作者
  • 单位
  • 陈静生
  • 北京大学城市与环境学系, 北京 100871
  • 张国梁
  • 北京大学城市与环境学系, 北京 100871
  • 穆岚
  • 北京大学城市与环境学系, 北京 100871
  • 霍文毅
  • 北京大学城市与环境学系, 北京 100871
  • 杨本津
  • 中国环境科学研究院
  • 摘要:提出并讨论了土壤的潜在还原容量、有效还原容量和条件还原容量等概念;通过对采自北京和唐山地下水饮用水源区3个包气带土壤样品的土柱淋滤实验,研究了土壤对水溶液中六价铬(Cr(VI))的还原作用,研究了上述土壤各种还原容量之间的关系及影响因素;探讨了向土壤中投加适量常见、无毒、价廉的还原性物质(如厩肥、FeS和风化煤等)以提高土壤还原能力的方法和将其应用于去除灌溉用污染地下水中六价铬(Cr(VI))的可能性。实验结果表明,在正常环境条件下,土壤的有效还原容量比土壤的潜在还原容量低3个数量级左右。向土壤中投加适量
  • Abstract:The concept of soil reduction capacity and its potential application to remediating of Cr contaminated soil and groundwater were discussed.Three types of reduction capacity of soil, i.e., the potential reduction capacity, available reduction capacity, and conditional reduction capacity were suggested.Three soil samples were collected from a groundwater pumping area and a Cr contaminated groundwater area in Tangshan City in north China.Soil column leaching experiments were conducted to evaluate the relations between the carious reduction capacity for Cr(Ⅵ) of soils.Approaches to increase the available reduction capacity of the soil by adding selected reductive materials, such as cattle manure, FeS and weathered coal were investigated.Results showed that the available reduction capacity of soil was about three orders of magnitude lower than the corresponding potential reduction capacity.Adding of selected reductive materials to soil could increase the available reduction capacity of soil. Compared with FeS and weathered coal, the cattle manure proved to be a better reductive material apparently with a prolonged reduction potential.

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