• 关键词：分析方法改进  土壤环境  底泥  有机卤化物  可提取态

• 基金项目：中国科学院“引进国外杰出人才”百人计划项目;国家重点基础研究发展规划项目(G1999011808);中国科学院知识创新工程重要方向项目(KZCX2SW416)

• 任丽萍
• 中国科学院沈阳应用生态研究所陆地生态过程重点实验室, 沈阳 110016

• 周启星
• 中国科学院沈阳应用生态研究所陆地生态过程重点实验室, 沈阳 110016

• 宋玉芳
• 中国科学院沈阳应用生态研究所陆地生态过程重点实验室, 沈阳 110016

• 李培军
• 中国科学院沈阳应用生态研究所陆地生态过程重点实验室, 沈阳 110016

• 摘要：选用甲苯正己烷、丙酮/正己烷两种混合溶剂作为污染土壤和底泥中可提取态有机卤化物的提取剂, 与乙酸乙脂作为提取剂进行三种溶剂超声法提取效率的比较, 采用微库仑法进行测定方法改进的研究.实验结果表明, 采用1∶9的丙酮/正己烷混合溶剂的提取效率较高, 其平均回收率与乙酸乙脂法接近, 而且回收率范围比乙酸乙脂法波动更小.以1∶9的丙酮/正己烷混合溶剂作为提取剂的方法还表明:无机可溶性卤化物对EOX测定不产生干扰, 分析方法的最低检出浓度范围为0.1—0.4mg(Cl)/kg, 测定范围为0—250.00mg(Cl)/kg, 添加标准样品的相对标准偏差为3.38%—5.09%.

• Abstract：Two mixed solvents, toluene/nhexane and acetone/Nhexane were used as extractant for determination of extractable organic halogens (EOX) in contaminated soils and sediments. A comparison of extractable efficiency between the two mixtures and ethyl acetate as an extractant was made using the improved method of ultrasonic extraction and microcoulometric determination. The experimental results showed that the extractable efficiency of acetone/Nhexane (V/V = 1∶9) was higher than that using other extractants and its recovery rate was close to that of ethyl acetate. There was a small fluctuation in the recovery rate when the acetone/Nhexane was used. It was also indicated that the soluble inorganic halogens does not interfered the determination of EOX, the lowest detectable concentration is 0.1—0.4mg(Cl)/kg, the determining range is 0—250 00mg(Cl)/kg, and the relative standard deviation is 3.38%—5.09 %, when 1∶9 acetone/nhexane is used as an extractant.

• Key words：analytical method improvement  soil environment  sediment  organic halogens  extractable form

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