污染控制技术及原理
闻瑞梅,葛伟伟.用185nm UV降解水中二苯甲酮和孔雀石绿[J].环境科学学报,2007,27(4):587-594
用185nm UV降解水中二苯甲酮和孔雀石绿
- A Study on the degradation path of diphenyl ketone and malachite green in water by 185nm UV irradiation
- 摘要：研究了185nm紫外光降解水中二苯甲酮和孔雀石绿和总有机碳(TOC)的规律.研究了浓度、体积、流速、pH等因素对二苯甲酮的降解效果的影响.通过改变污染物初始浓度、体积、流量、pH值以及添加无机离子来讨论185nm紫外光对孔雀石绿的降解效果,探讨了降解的最佳条件.降解达到了治理水中二苯甲酮和孔雀石绿污染的目的.用这种方法降解水中二苯甲酮和孔雀石绿,去除率能够达到99.9%以上,是一种非常有效的治理污染方法.实验同时验证了185nmUV降解水中的二苯甲酮和孔雀石绿符合准一级动力学规律.
- Abstract：In this paper the reduction process of diphenyl ketone, malachite green, and total organic carbon (TOC) in water by using 185nm UVirradiation was studied. The effect of initial pollutant concentration, volume, flow rate and initial pHvalues on diphenyl ketone degradation was discussed. The effectiveness of degradation of malachite green was studied by changing initial malachite green concentration, volume, flow rate, initial pHvalues and concentration of added inorganic ions. The optimum condition for removal of diphenyl ketone and malachite green in water was discussed. The 185nm UVirradiation has been proved to be effective for removal of diphenyl ketone and malachite green in water with efficiency of above 99.9%. The kinetics rule for degradation of diphenyl ketone and malaclite green is discussed. The degradation reaction is found to fot for pseudo-first order reaction.
摘要点击次数： 2464 全文下载次数： 4171
