污染控制技术及原理
何新慧,张立卿,刘雪飞,王志盈.双SBR脱氮除磷工艺的数学模型分析[J].环境科学学报,2008,28(6):1085-1092
双SBR脱氮除磷工艺的数学模型分析
- Kinetic analysis of a two sludge-SBR denitrifying and phosphorus removing system
- 基金项目:国家自然科学基金项目(No.50178059,50008014)
- 何新慧
- 1. 西安建筑科技大学环境与市政工程学院, 西安 710055; 2. 中冶东方工程技术有限公司, 包头 014010
- 张立卿
- 西安建筑科技大学环境与市政工程学院, 西安 710055
- 刘雪飞
- 西安建筑科技大学环境与市政工程学院, 西安 710055
- 王志盈
- 西安建筑科技大学环境与市政工程学院, 西安 710055
- 摘要:应用ASM2和Delft代谢模型,结合双SBR(A2-SBR)脱氮除磷系统的特点,建立了数学模拟器,并将其运用于双SBR脱氮除磷系统运行特性的动力学分析.主要探讨了不同泥龄、碳氮比、碳磷比对系统的影响,并从模型的角度进行了分析.结果表明,利用ASM2和Delft代谢模型结合所建立的数学模拟器可以对双SBR(A2-SBR)脱氮除磷系统进行模拟.双SBR中具有脱氮除磷功能的A2-SBR的运行参数是关键因素,最佳污泥龄为9~12d时,碳氮比为3.75左右,碳磷比大于15条件下,双SBR运行正常,能得到较好的处理效果.当系统在泥龄大于12d条件下运行时,由于PAO储存了大量的聚合态磷(XPP/XPAO接近0.5)造成除磷效率降低.同样的原因也导致了碳磷比值低于15时,PAO的聚磷反应变慢或停止.
- Abstract:Based on the Delft metabolic model and Activated Sludge Model No.2(ASM2),a mathematical model was developed to characterize a two sludge-sequencing batch reactor(SBR)(A2-SBR).The model predicts and simulates the kinetics of a denitrifying phosphorus removal system at different sludge retention times(SRT),carbon source-to-ammonia concentration ratios(C/N)as well as carbon source-to-phosphate concentration ratios(C/P).The predictive capability of the proposed model was excellent as evidenced from comparison of experimental results and model simulations.Optimal effects were achieved with an influent C/Nratio of 3.75(g·g-1),a C/Pratio of more than 15(g·g-1)and an SRT of 9~12 days.At the same time,the reasons for low efficiency nitrogen and phosphorus removal were analyzed.When the SRT is more than 12 days,large amounts of internal polyphosphate(XPP/XPAO approaching 0.5)led to a low phosphorus removal rate.Phosphorus removal slowed or even stopped when the C/Pratio was less than 15.
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