• 关键词：同步脱氮除硫  一体式厌氧-好氧反应器  单质硫

• 基金项目：国家高技术研究发展计划(863)资助项目((No.2002AA601210)

• 竺美
• 1. 四川大学建筑与环境学院, 成都 610065; 2. 四川省环境保护科学研究院, 成都 610041

• 杨平
• 四川大学建筑与环境学院, 成都 610065

• 郭勇
• 四川大学建筑与环境学院, 成都 610065

• 郑德会
• 四川大学建筑与环境学院, 成都 610065

• 摘要：采用一体式厌氧-好氧流化床反应器处理含氮和含硫化物的废水,分别考察了硫氮比(硝氮和亚硝氮)、碳氮比(氨氮)等因素对同步脱氮除硫效果的影响,并对厌氧区固体产物进行了分析.实验结果表明:混养条件下获得了较好的脱氮、脱硫、去除COD的效果;S^2-浓度增加对厌氧COD去除、反硝化过程无显著影响;当S^2-浓度小于4.6mmol·L^-1时,对厌氧氨氮去除有一定的促进作用.S/N(NO₃^--N和NO₂^--N)在0.2～1.7范围内,可以获得20%～75%单质硫转化率.C/NH₄⁺-N的降低对厌氧脱氮效果无明显影响,但可促进硫化物的去除.X射线衍射分析表明,厌氧区固体产物为单质硫.好氧进水中硫化物浓度增加对好氧区COD去除影响不明显,但S^2-浓度大于15mg·L^-1时会对硝化过程产生明显抑制.

• Abstract：Anaerobic-aerobic integrated reactors were used to treat wastewater containing nitrogen and sulfide.The effect of C/NH₄⁺-N and S/N(NO₃^--N and NO₂^--N)on simultaneous biological removal of nitrogen and sulfur was studied.The results show that simultaneous removal of sulfide,nitrogen and COD as well as elemental sulfur accumulation could be achieved under mixotrophic conditions.It was shown that an increase of sulfide concentration showed little inhibition of COD removal rate and denitrification in the anaerobic area.The NH₄⁺-N removal effect was promoted when the sulfide concentration was less than 4.6mmol·L^-1.A 20%～75% S⁰ production rate was achieved when S/N was 0.2～1.7.The decrease of C/NH₄⁺-N had no obvious effect on denitrification,but it promoted sulfide removal.The X-ray diffraction result indicates that the product from the anaerobic area is elemental sulfur.In the aerobic area,the increase of sulfide concentration had no obvious influence on CODremoval,while it inhibited the nitrification process remarkably at sulfide concentrations more than 15 mg·L^-1.

• Key words：simultaneous desulfidation and denitrogenation process  elemental sulfur  anaerobic-aerobic fluidized bed of integrated reactor

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