研究报告
贺艳,段海静,王广华,郭昌胜,王玉秋.3D介孔TiO2微米球的制备及其光催化降解双酚A的研究[J].环境科学学报,2011,31(10):2179-2184
3D介孔TiO2微米球的制备及其光催化降解双酚A的研究
- Preparation of 3D mesoporous titanium dioxide microspheres and its photocatalytic degradation activity on bisphenol A
- 基金项目：国家水体污染控制与治理科技重大专项(No. 2008ZX07314-003);教育部博士点基金(No. 200800550011)
- 作者
- 单位
- 贺艳
- 南开大学环境科学与工程学院, 天津 300071
- 段海静
- 河南大学环境与规划学院, 开封 475000
- 王广华
- 开封市环境监测站, 开封 475000
- 郭昌胜
- 南开大学环境科学与工程学院, 天津 300071
- 王玉秋
- 南开大学环境科学与工程学院, 天津 300071
- 摘要：利用水热方法,无需模板一步合成3D介孔TiO2光催化剂.然后采用X射线衍射(XRD)、透射电子显微镜(TEM)、高分辨电子显微镜(HRTEM)和N2吸附-解吸BET 技术对其组织结构进行表征,以双酚A为目标物对比介孔TiO2光催化剂和市售P25的光催化性能,并研究了不同温度下TiO2 的相变及热重分析(TGA).结果表明,于400℃焙烧的TiO2介孔微球为锐钛矿型结构,其粒径为4.2 nm,比表面积达到159.4 m2·g-1. 800 ℃焙烧后的TiO2介孔微球转变为金红石矿型结构.实验表明,以300 W 高压汞灯为光源进行光催化实验,400 ℃焙烧后的TiO2介孔微球1 h 内可使浓度为20 mg·L-1 BPA溶液的降解率可达100%, 高于市售P25粉体的降解率.
- Abstract：The 3D mesoporous TiO2 microspheres were fabricated in a one-step hydrothermal process without templates, and the microspheres were subsequently characterized by XRD, TEM, HRTEM and BET techniques. The photocatalytic degradation activity of the 3D mesoporous TiO2 microspheres was evaluated by comparison to the commercial P25 on the degradation of bisphenol A (2,2-bis(4-hydroxyphenyl)propane, BPA), and the phase transformation of TiO2 at different temperatures and thermal gravimetric analysis (TGA) were also studied. The results showed that mesoporous TiO2 microspheres calcined at 400 ℃ were anatase phase, with the diameter of 4.2 nm and the specific surface area of 159.4 m2·g-1. The crystal form of mesoporous TiO2 microspheres was transformed into rutile phase under calcination at 800 ℃. The irradiation experiments using a 300 W high pressure mercury lamp as the light source showed that the degradation efficiency of 20 mg·L-1 BPA solution was up to 100% within 1 h using the mesoporous TiO2 microspheres calcined at 400 ℃ as catalyst, which was superior to commercial P25 powders.
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